Get a coolant test kit (hydrometer) and check the coolant/water ratio (specific gravity). Coolant actually de-rates the cooling capacity of the water, and running too much coolant will make the motor run hot. You should only run enough coolant in your water to satisfy the winter freeze protection in your area. I run mine to meet a -5F degree wintertime temperature. Adding more is just wasting coolant and further de-rating your water's ability to transfer heat. I mention this because sometimes people "top off" their cooling systems with straight coolant, and over time...you can end up way past the optimum ratio. I've seen people try to run straight coolant, and they usually don't get three miles down the road before they overheat. Most auto parts stores now sell pre-mixed 50/50 coolant...which IMO is still way too much (unless you live in Alaska). It should be closer to 70/30 for us guys here in the midwest.
Dextron provides boiling and freezing protection, corrosion protection, and lubrication for your water pump. Water does the cooling.